(4,4′-Dimethyl-2,2′-bipyridine-κ2 N,N′)(dimethylformamide-κO)diiodidocadmium
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چکیده
In the title compound, [CdI2(C12H12N2)(C3H7NO)], the Cd(II) cation is five-coordinated in a distorted trigonal-bipyramidal configuration by two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-formamide ligand and two I(-) anions. π-π stacking between pyridine rings of adjacent mol-ecules [centroid-centroid distance = 3.666 (3) and 3.709 (4) Å] stabilizes the three-dimensional structure.
منابع مشابه
Diammonium bis[(2-aminoacetato-κ2 N,O)(2,2′-bipyridine-κ2 N,N′)(N,N-dimethylformamide-κO)copper(II)] hexacosaoxidooctamolybdate(VI)
The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa-molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2'-bipyridine and a 2-amino-acetate ligands in the basal plane and by an O atom of N,N-dimethyl-formamide in the apical posit...
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In the title compound, [CdBr(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal-bipyramidal geometry by two N atoms from one 4,4'-dimethyl-2,2'-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intra-molecular C-H⋯O hydrogen bond occurs between the DMBP and DMSO ligands. π-π stacking between pyridine r...
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